Mineralogical and morphological constraints on the reduction of Fe(III) minerals by Geobacter sulfurreducens     

R.S. Cutting  V.S. Coker  J.W. Fellowes  J.R. Lloyd  D.J. Vaughan 《Geochimica et cosmochimica acta》2009,73(14):4004-6858

The biologically-mediated reduction of synthetic samples of the Fe(III)-bearing minerals hematite, goethite, lepidocrocite, feroxhyte, ford ferrihydrite, akaganeite and schwertmannite by Geobacter sulfurreducens has been investigated using microbiological techniques in conjunction with X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS). This combination of approaches offers unique insights into the influence of subtle variations in the crystallinity of a given mineral on biogeochemical processes, and has highlighted the importance of (oxyhydr)oxide crystallite morphology in determining the changes occurring in a given mineral phase. Problems arising from normalising the biological Fe(III) reduction rates relative to the specific surface areas of the starting materials are also highlighted. These problems are caused primarily by particle aggregation, and compounded when using spectrophotometric assays to monitor reduction. For example, the initial rates of Fe(III) reduction observed for two synthetic feroxyhytes with different crystallinities (as shown by XRD and TEM studies) but almost identical surface areas, differ substantially. Both microbiological and high-resolution TEM studies show that hematite and goethite are susceptible to limited amounts of Fe(III) reduction, as evidenced by the accumulation of Fe(II) during incubation with G. sulfurreducens and the growth of nodular structures on crystalline goethite laths during incubation. Lepidocrocite and akaganeite readily transform into mixtures of magnetite and goethite, and XRD data indicate that the proportion of magnetite increases within the transformation products as the crystallinity of the starting material decreases. The presence of anthraquinone-2,6-disulfonate (AQDS) as an electron shuttle increases both the initial rate and longer term extent of biological Fe(III) reduction for all of the synthetic minerals examined. High-resolution XPS indicates subtle but measurable differences in the Fe(III):Fe(II) ratios at the mineral surfaces following extended incubation. For example, for a poorly crystalline schwertmannite, deconvolution of the Fe2p_3/2 peak suggests that the Fe(III):Fe(II) ratio of the near-surface regions varies from 1.0 in the starting material to 0.9 following 144 h of incubation with G.sulfurreducens, and to 0.75 following the same incubation period in the presence of 10 μM AQDS. These results have important implications for the biogeochemical cycling of iron.  相似文献   

Spatial–temporal changes in Andean plateau climate and elevation from stable isotopes of mammal teeth     

John Bershaw  Carmala N. Garzione  Pennilyn Higgins  Bruce J. MacFadden  Frederico Anaya  Herculano Alvarenga 《Earth and Planetary Science Letters》2010,289(3-4):530-538

Paleoelevation constraints from fossil leaf physiognomy and stable isotopes of sedimentary carbonate suggest that significant surface uplift of the northern Andean plateau, on the order of 2.5 ± 1 km, occurred between ～ 10.3 and 6.4 Ma. Independent spatial and temporal constraints on paleoelevation and paleoclimate of both the northern and southern plateau are important for understanding the distribution of rapid surface uplift and its relation to climate evolution across the plateau. This study focuses on teeth from modern and extinct mammal taxa (including notoungulates, pyrotheres, and litopterns) spanning ～ 29 Ma to present, collected from the Altiplano and Eastern Cordillera of Bolivia (16.2°S to 21.4°S), and lowland Brazil. Tooth enamel of large, water-dependent mammals preserves a record of surface water isotopes and the type of plants that animals ingested while their teeth were mineralizing. Previous studies have shown that the δ¹⁸O of modern precipitation and surface waters decrease systematically with increasing elevations across the central Andes. Our results from high elevation sites between 3600 and 4100 m show substantially more positive δ¹⁸O values for late Oligocene tooth samples compared to < 10 Ma tooth δ¹⁸O values. Late Oligocene teeth collected from low elevation sites in southeast Brazil show δ¹⁸O values similar (within 2‰) to contemporaneous teeth collected at high elevation in the Eastern Cordillera. This affirms that the Andean plateau was at a very low elevation during the late Oligocene. Late Oligocene teeth from the northern Eastern Cordillera also yield consistent δ¹³C values of about ? 9‰, indicating that the environment was semi-arid at that time. Latitudinal gradients in δ¹⁸O values of late Miocene to Pliocene fossil teeth are similar to modern values for large mammals, suggesting that by ～ 8 Ma in the northern Altiplano and by ～ 3.6 Ma in the southern Altiplano, both regions had reached high elevation and established a latitudinal rainfall gradient similar to modern.  相似文献   

Fundamental changes in the activity of the natrocarbonatite volcano Oldoinyo Lengai, Tanzania     

Matthieu Kervyn  Gerald G. J. Ernst  Jörg Keller  R. Greg Vaughan  Jurgis Klaudius  Evelyne Pradal  Frederic Belton  Hannes B. Mattsson  Evelyne Mbede  Patric Jacobs 《Bulletin of Volcanology》2010,72(8):913-931

On September 4, 2007, after 25 years of effusive natrocarbonatite eruptions, the eruptive activity of Oldoinyo Lengai (OL), N Tanzania, changed abruptly to episodic explosive eruptions. This transition was preceded by a voluminous lava eruption in March 2006, a year of quiescence, resumption of natrocarbonatite eruptions in June 2007, and a volcano-tectonic earthquake swarm in July 2007. Despite the lack of ground-based monitoring, the evolution in OL eruption dynamics is documented based on the available field observations, ASTER and MODIS satellite images, and almost-daily photos provided by local pilots. Satellite data enabled identification of a phase of voluminous lava effusion in the 2 weeks prior to the onset of explosive eruptions. After the onset, the activity varied from 100 m high ash jets to 2–15 km high violent, steady or unsteady, eruption columns dispersing ash to 100 km distance. The explosive eruptions built up a ∼400 m wide, ∼75 m high intra-crater pyroclastic cone. Time series data for eruption column height show distinct peaks at the end of September 2007 and February 2008, the latter being associated with the first pyroclastic flows to be documented at OL. Chemical analyses of the erupted products, presented in a companion paper (Keller et al. 2010), show that the 2007–2008 explosive eruptions are associated with an undersaturated carbonated silicate melt. This new phase of explosive eruptions provides constraints on the factors causing the transition from natrocarbonatite effusive eruptions to explosive eruptions of carbonated nephelinite magma, observed repetitively in the last 100 years at OL.  相似文献   

Spatial assessment of fishing effort around European marine reserves: implications for successful fisheries management   总被引：7，自引：0，他引：7  

Stelzenmüller V  Maynou F  Bernard G  Cadiou G  Camilleri M  Crec'hriou R  Criquet G  Dimech M  Esparza O  Higgins R  Lenfant P  Pérez-Ruzafa A 《Marine pollution bulletin》2008,56(12):2018-2026

We examined the spatial dynamic of artisanal fishing fleets around five European marine protected areas (MPAs) to derive general implications for the evaluation of MPAs as fisheries management tools. The coastal MPAs studied were located off France, Malta and Spain and presented a variety of spatial designs and processes of establishment. We developed a standardized methodology to define factors influencing effort allocation and to produce fishing effort maps by merging GIS with geostatistical modelling techniques. Results revealed that in most cases the factors “distance to the no-take”, “water depth”, and “distance to the port” had a significant influence on effort allocation by the fishing fleets. Overall, we found local concentration of fishing effort around the MPA borders. Thus, neglecting the pattern of fishing effort distribution in evaluating MPA benefits, such as spillover of biomass, could hamper sound interpretation of MPAs as fisheries management tools.  相似文献   

Suppression of swelling associated with ettringite formation in lime stabilized sulphate bearing clay soils by partial substitution of lime with ground granulated blastfurnace slag (GGBS)   总被引：1，自引：0，他引：1  

S. Wild  J. M. Kinuthia  G. I. Jones  D. D. Higgins 《Engineering Geology》1999,51(4):1867-277

Ettringite related swelling in lime-stabilized sulphate bearing clay soil systems has only been reported within the last decade although similar expansive behaviour has been reported in concrete over many years. The use of ground granulated blastfurnace slag (GGBS), an industrial by-product, is well established as a binder in many cement applications where it provides enhanced durability and high resistance to sulphate attack. This paper reports on efforts to extend the use of GGBS to highway and other foundation layers by determining the beneficial effect of the suppression of swelling of lime-stabilized clay soils, particularly in the presence of gypsum. The paper describes the results of laboratory tests on lime-stabilized kaolinite containing different levels of added gypsum and on lime-stabilized gypsum (selenite) bearing Kimmeridge Clay to which, in both cases, the lime has progressively been substituted with GGBS. The tests determine the linear expansion behaviour of compacted cylinders, during moist curing in a humid environment at 30°C and during subsequent soaking in de-ionized water. The results illustrate that substitution of lime with GGBS produces significant reduction in linear expansion of lime-stabilized clay soils particularly those containing gypsum.  相似文献   

Wood export prediction at the watershed scale          下载免费PDF全文

Anne Senter  Gregory Pasternack  Hervé Piégay  Matthew Vaughan 《地球表面变化过程与地形》2017,42(14):2377-2392

Wood export from a watershed is a function of peak annual discharge, but one hydrologic relationship alone does not fully explain observed variability. Consideration of physical processes that influence the amount of wood available for transport is needed. However, wood recruitment, storage, mobilization, breakage, and transport rates and processes remain difficult to quantify. A theoretical wood transport equation focused on variations in discharge was the motivation for investigation into watershed‐specific wood export rates. Herein, multiplicative coefficients categorized by water year type are developed, paired with the equation, and validated to provide a new method for prediction of wood export at the watershed scale. The coefficients are defined as representing a broad suite of watershed processes that encompass spatio‐temporally variable scales. Two complementary datasets from the 1097 km² mountainous North Yuba River, California watershed were used. Wood surveys above New Bullards Bar Reservoir yielded a wood availability estimate of 250 000–300 000 m³ along the channel network. Annual wood export into the reservoir was field‐surveyed in 2010, 2012 and 2013, and estimated in seven years via remotely sensed images over the 30 year study period of water years 1985–2014. Empirical, watershed‐scale wood export rates ranged from 0.3–5.6%. Comparison of predicted quantities using the new DVWP (discharge variations modified by watershed processes) wood export equation to observed wood export quantities resulted in an aggregate error rate of ±10%. When individual wood export quantities were compared, predicted to observed varied by 0.5–3.0 times. Total wood export of 59 000–71 000 m³ was estimated over the 30 year period, yielding a rate of 1.8 to 2.2 m³/year/km². Wood export predictive capabilities at the watershed scale may help water resource and regulatory agencies plan for wood transfers to augment downstream ecosystems. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Chemical remobilization of contaminant metals within floodplain sediments in an incising river system: implications for dating and chemostratigraphy     

K. A. Hudson-Edwards  M. G. Macklin  C. D. Curtis  D. J. Vaughan 《地球表面变化过程与地形》1998,23(8):671-684

Metals such as Pb, Zn, Cd and Cu from historical mining activity have been used as stratigraphic markers for dating and provenancing vertically accreted, fine-grained floodplain overbank deposits. This study presents evidence for chemical remobilization of these metals within overbank sediments in the Tyne basin, UK. The evidence includes: breakdown of metal-bearing minerals (sulphides, carbonates, iron and manganese oxyhydroxides); shifts of chemical fractions within zones of relatively low pH towards more soluble and reactive phases; and accumulation of secondary iron and manganese oxyhydroxides at levels related to fluctuating water-table levels or to the breakdown of organic matter. All of this suggests that fine, centimetre-scale, chemostratigraphy using metal concentrations and ratios is unlikely to provide reliable data in river systems that have experienced, or are experiencing, major changes in water-table levels, or pedogenesis. Coarse tens of centimetre- to metre-scale, chemostratigraphy, when applied with caution, may still provide a means of delineating contaminated units. © 1998 John Wiley & Sons, Ltd.  相似文献   

X-ray reflection in the narrow-line Seyfert 1 galaxy 1H 0707–495     

A. C. Fabian  G. Miniutti  L. Gallo  Th. Boller  Y. Tanaka  S. Vaughan  R. R. Ross 《Monthly notices of the Royal Astronomical Society》2004,353(4):1071-1077

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Stability of openings in jointed rock     

David K. Vaughan  J. Isenberg 《国际地质力学数值与分析法杂志》1991,15(6):433-442

The slide line approach is combined with the finite element method to represent the action of a removable block on a lined tunnel. The present paper examines the strength and ductility required of the tunnel liner to resist the forces imposed by a block when the surrounding rock mass is subjected to explosive loading. Key block theory developed by Goodman and Shi provides the conceptual framework for simplifying a general jointed domain to a manageable size for analysis with finite element models.  相似文献   

The narrow-line quasar NAB 0205 + 024 observed with XMM–Newton     

L. C. Gallo  Th. Boller  W. N. Brandt  A. C. Fabian  S. Vaughan 《Monthly notices of the Royal Astronomical Society》2004,355(2):330-335

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